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| Tags: mechanics, quantum, relativistic |
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Pmb wrote: I'm looking for examples of closed form solutions, and their derivations, to the Dirac equation. Does anyone know of any online resources Try http://membres.lycos.fr/pvarni/dirac/rapport.html I entered "Solution Direac Equation" to Google and got many hits. Check them out. Bob Kolker |
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"Robert J. Kolker" wrote in message ... Pmb wrote: I'm looking for examples of closed form solutions, and their derivations, to the Dirac equation. Does anyone know of any online resources Try http://membres.lycos.fr/pvarni/dirac/rapport.html I entered "Solution Direac Equation" to Google and got many hits. Check them out. Bob Kolker Thanks Bob. I'm also curious as to something - The Hamiltonian for a relativistic charged particle in an electromagnetic field is given by H = sqrt[(cP - eA)^2 + m^2 c^4] + e*Phi where P = canonical momentum e = charge A = vector potential m = rest mass Phi = Coulomb potential I've seen two discussions in the texts that I have on this. One is Cohen-Tannoudji. They do the special case of the Hydrogen atom. However they do it using perturbation theory. The rule for a function of an operator F(A) is to expand the function F(z) in a power series and then substitute A - F(A). In this case Hamiltonion the operator for the canonical momentum is inserted into the Hamiltonian above. It's been close to a decade since I've done this so please bear with me. I've only seen the solution approximated, and then only by using the above Hamiltonitan in Schrodinger's equation and then using perturbation theory. This is what Cohen-Tannoudji do. Since the series is an infinite power series it appears there's no closed form solution. Is that true? I have another QM text that states that when the operators are placed in the above Hamiltonian the result is not symetric in space and time derivatives. But it doesn't say that it can't be done. Is this what Cohen-Tannoudji is doing?? (see page 1213) I'm also interested in finding an example of an eigenvalue problem F(A)Psi = F(a)Psi where there's no closed form expression for Psi Does anyone know of an example? Pmb |
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Pmb:
I've seen two discussions in the texts that I have on this. One is Cohen-Tannoudji. They do the special case of the Hydrogen atom. However they do it using perturbation theory. The rule for a function of an operator F(A) is to expand the function F(z) in a power series and then substitute A - F(A). Which is why dirac didn't do it that way. Expanding the square root leads to an intractable problem. In this case Hamiltonion the operator for the canonical momentum is inserted into the Hamiltonian above. It's been close to a decade since I've done this so please bear with me. I've only seen the solution approximated, and then only by using the above Hamiltonitan in Schrodinger's equation and then using perturbation theory. This is what Cohen-Tannoudji do. Find a copy of bjorken and drell, vol I. They address all of the above and more in the first 6 pages and without the verbose rambling found in cohen-tannoudji. You can also look in schiff, or just about any other decent quantum mechanics, particle or introductory field theory text. Since the series is an infinite power series it appears there's no closed form solution. Is that true? No, it obviously isn't true, since the dirac equation is a solution in closed form. Choose coefficients for p and m and rewrite the hamiltonian as: E^2 = [(a.p) + (bm)] ^2 Require that: [(a.p) + (bm)] ^2 = p^2 + m^2 Solve for the coefficients a_i and b from the anti-commutation relations that have to be satisfied for the cross terms to disappear. You can also otain different solutions if you factor it directly: E^2\Psi = (p + im)(p - im)\Psi But interpreting the solution to those two differential equations is up to you. I have another QM text that states that when the operators are placed in the above Hamiltonian the result is not symetric in space and time derivatives. But it doesn't say that it can't be done. Is this what Cohen-Tannoudji is doing?? (see page 1213) From what you've written, cohen-tannoudji appears to have given only a low energy approximation to a relativistic hamiltonian. I'm also interested in finding an example of an eigenvalue problem F(A)Psi = F(a)Psi where there's no closed form expression for Psi Does anyone know of an example? Pick one. Just about any operator will do. Very few eigenvalue problems give solutions which are expressable in closed form. That's why everyone does perturbation theory and manipulates operators assuming plane waves rather than solves differential equations for the exact wavefunctions. |
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First off - Let me state right here and now so that nobody gets the
wrong idea. I should have mentioned this the other day but didn't think of it. I've only done the rudimentary stuff when it comes to relativistic quantum mechanics. I.e. simple stuff that can be found in, say Liboff's "Relativistic Quantum Mechanics" section. And it's been over 10 years since I've done perturbation theory. So I make no claims at being anything but just beginning to learn/brush up/re-learn this stuff, i.e. Klein-Gordon Eq. etc. That said......... (Bilge) wrote in message ... Pmb: I've seen two discussions in the texts that I have on this. One is Cohen-Tannoudji. They do the special case of the Hydrogen atom. However they do it using perturbation theory. The rule for a function of an operator F(A) is to expand the function F(z) in a power series and then substitute A - F(A). Which is why dirac didn't do it that way. Expanding the square root leads to an intractable problem. Why? Seems to me that this is what is used in perturbation theory to examine the fine-structure and hyperfine-struction. Cohen-Tannoudji expand the momentum in terms of a power series.In fact this is what they seem to be doing in the advanced quantum mechanice course at CalTech. http://minty.caltech.edu/Ph195/entrypage.htm In fact they refer to Cohen-Tannoudji as well http://minty.caltech.edu/Ph195/wednesday1c.pdf Find a copy of bjorken and drell, vol I. They address all of the above and more in the first 6 pages and without the verbose rambling found in cohen-tannoudji. You can also look in schiff, or just about any other decent quantum mechanics, particle or introductory field theory text. Thank you. Since the series is an infinite power series it appears there's no closed form solution. Is that true? No, it obviously isn't true, since the dirac equation is a solution in closed form. If it's not true then why doesn't Cohen-Tannoudji given the energy values of the hydrogen atom in terms of a closed form? Choose coefficients for p and m and rewrite the hamiltonian as: E^2 = [(a.p) + (bm)] ^2 Require that: [(a.p) + (bm)] ^2 = p^2 + m^2 Solve for the coefficients a_i and b from the anti-commutation relations that have to be satisfied for the cross terms to disappear. While I understand that in principle that may be true, I see no reason to assume that it can be done without numerical methods or using perturbation theory etc. Do those texts you mention derive a closed form solution? From what you've written, cohen-tannoudji appears to have given only a low energy approximation to a relativistic hamiltonian. They refer to it as the "weakly relativistic domain." Even so it seems that they're using that Hamiltonian, even if its just only low energy it seems like a valid approach - even if your just interested in things like the fine-structure. My intent here is to investigate claims made regarding this Hamiltonian, H = sqrt[ (cP - eA)^2 + m^2 c^4] + e*Phi I never said anything about this with respect to rel-QM. The claim was that the square root of an operator is meaningless. While I don't know exacatly if and how I'm also interested in finding an example of an eigenvalue problem F(A)Psi = F(a)Psi where there's no closed form expression for Psi Does anyone know of an example? Pick one. Just about any operator will do. Very few eigenvalue problems give solutions which are expressable in closed form. Damn! I missed the most obvious one. And it was staring me right in the face. If Psi is an energy eigenfunction, then exp[-itH/hbar]Psi = exp[-itE/hbar]Psi Thank you bilge. This arose from a claim that such an equation as this is a differential equation of infinite power and the person wsuggested that it was nonsense or meaningless or whatever. Pmb |
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Gauge:
Which is why dirac didn't do it that way. Expanding the square root leads to an intractable problem. Why? Because you have an infinite number of terms. If you expand the square root, you get: E = m sqrt(1 + (p/m)^2) = m ( 1 + (1/2)(p/m)^2 - (1/4)(1/2!)(p/m)^4 + ...) E - m = (p/m)^2 - (1/8)(p/m)^4 + ... The first term is the schroedinger equation (after dividing everything by m). What do you want to d about the terms p^4, p^6, p^8, p^10, etc? Moreover, the hamiltonian is non-local, because it contains derivatives to all orders, so the space and time variables are not on equal footing. Seems to me that this is what is used in perturbation theory to examine the fine-structure and hyperfine-struction. Cohen-Tannoudji expand the momentum in terms of a power series.In fact this is what they seem to be doing in the advanced quantum mechanice course at CalTech. That's rather illusory. You are not getting the true significance of relativity and you aren't really getting the fine and hyperfine structure from the theory. What you are getting are only the terms which contribute to the kinetic energy from the v/c dependence. The spin is put in by hand. However, the spin is the only really interesting feature that is novel to quantum mechanics. You'll notice that your reference merely asserts the spin-orbit term and then uses the relation for total J = L+S to rewrite L^2 as J^2 - S^2 - 2L.S. While that is useful to know, since it's a simple way to obtain the (mostly) correct energy levels, it really has little to do with the relativistic aspect of quantum mechanics. The proper way to do that is to start with the dirac equation: H^2\Psi = E^2\Psi = [(a.p) + (bm)]^2\Psi = [p^2 + m^2]\Psi E^2 = (1/2)[a_i a_j + a_j a_i] p_i p_j + [a_i b + b a_i]m p_i + (bm)^2 which immediately gives: a_i b + b a_i = 0, (a_i)(a_i) = b^2 = 1 [a_i, a_j]_+ = 2\delta_jk ([ ]_+ means anti-commutator) Solving for the a_i gives you (at the least) 4x4 matricies with the pauli matricies \delta_i on the off-diagonals of a 2x2 matrix and the matrix b as I and -I (2x2 identity matrix) on the diagonals of a 2x2 matrix: [ 0 \delta_i ] [ I 0 ] a_i = [ ] b = [ ] [ \delta_i 0 ] [ 0 -I ] So, first of all, from obtaining the exact relativistic hamiltonian, you get the spin automatically. Since the matrices are 4 x 4, the soultion is a set of 4 coupled first order differential equations. Now if you you substitute the potentials into the dirac hamiltonian, rather than the equation you expanded, you get: E\Psi = (a.(p - eA) + bm - e\phi)\Psi Using the representation for the a_i and b above and writing \Psi as a two-component column matrix (spinor), i.e., [Q] \Psi = [ ] Where Q and X are each two component wavefunctions, [X] (Q is called the "large component" and X is called the "small component" of the wavefunction, \Psi) which after some algebra I'm not going to reproduce, gives in the limit for E mc^2: X = (1/2mc)\delta.(p-eA)Q, which gives an equation for the spinor Q that uncouples the two equations for each spinor: X = (a.(p-eA)/2m) Q Which plugging back into the equation for Q, gives: E Q = [(a.(p-eA))^2/2m + e\phi] Q Write P == p - eA and you have the (a.P)^2 which since the a_i are just the pauli matrices, \delta_i, can be reduced using the identity for two vectors u and v: \delta.u \delta .v = u.v + i\delta . (u x v) In this case both u and v are P so write out P as (p - eA) and you get: (\delta.P)^2 = (p - eA)^2 - i\delta .(p x A) The hamiltonian given in cohen-tannoudji contains _only_ the term (p-eA)^2. It does not contain the second term above. That was partially handwaved in by asserting the existence of the spin. From this, you can multiply out the terms and use the fact that p = -i\hbar\grad to find that the electron has a magnetic moment, i\delta.(i\hbar\grad x A) = -\hbar \delta . B Bjorken and Drell solve the real hydrogen atom and give the additional splitting from the lamb shift (vacuum polarization). [...] No, it obviously isn't true, since the dirac equation is a solution in closed form. If it's not true then why doesn't Cohen-Tannoudji given the energy values of the hydrogen atom in terms of a closed form? The energy eigenvaluse are not the same thing as writing the eigenvalue equation in closed form. Cohen-Tannoudji writes an approximation to the hamiltonian and then inserts some stuff obtained from the dirac equation. The point is that you can get the exact equation and solve that instead. How you solve the exact hamiltonian depends upon whether or not you can solve that equation in closed form. In general, you can't so what you do is perform what's called a "foldy-wouthuysen transformation", which decouples the large and small components by assuming a unitary transform of the form: H' = \exp(iS) H \exp(-iS) and then solving for S using a power series expansion of the exponential and rewriting the terms as an infinite series of iterated commutators. [(a.p) + (bm)] ^2 = p^2 + m^2 Solve for the coefficients a_i and b from the anti-commutation relations that have to be satisfied for the cross terms to disappear. While I understand that in principle that may be true, I see no reason to assume that it can be done without numerical methods or using perturbation theory etc. Do those texts you mention derive a closed form solution? You need to specify what you mean by "closed form solution". In one place it appears you mean an expression for the hamiltonian and in others it appears to mean an expression for the eigenvalues. From what you've written, cohen-tannoudji appears to have given only a low energy approximation to a relativistic hamiltonian. They refer to it as the "weakly relativistic domain." Even so it seems that they're using that Hamiltonian, even if its just only low energy it seems like a valid approach - even if your just interested in things like the fine-structure. It's fine for that, but in doing so, it's very misleading to imply that it represents a relativistic equation, since it merely asserts the parts that come from relativity (apart from the expansion of the sqaure root). You could just as easily assert those terms and tack them on to the schroedinger equation. This is one of the reasons that I object to that book. What they are doing is essentially showing you how to do perturbation theory and obscuring the point by introducing it as relativity, but then assert all of the stuff that really comes from the relativistic equations. So, the introduce pages of material which are extraneous to the point they are making leaving one to wonder what the example was supposed to address. Since that book has the absolute worst treatment of addition of angular momentum that I have ever encountered, they would have been better off explaining addition of angular momentum, which happens to be important for the example at hand. My intent here is to investigate claims made regarding this Hamiltonian, H = sqrt[ (cP - eA)^2 + m^2 c^4] + e*Phi I never said anything about this with respect to rel-QM. The Subject header you wrote plainly says: "Subject: Relativistic Quantum Mechanics" The claim was that the square root of an operator is meaningless. It's obviously not meaningless, as dirac demonstrated by showing that it gives you the electron spin and antimatter. Solving it by expanding the square root just happens to be an extremely cumbersome way to go about it and doesn't give any physical insight as to what the terms mean. This arose from a claim that such an equation as this is a differential equation of infinite power and the person wsuggested that it was nonsense or meaningless or whatever. It's not meaningless. It took someone like dirac (if there actually could be anyone like dirac), to find a way to make that expression meaningful and interpret the terms. The klein-gordon equation was proposed very early - early enough that the schroedinger equation might have been deemed irrelevant or at least given less importance - but it couldn't be interpreted because of the second order time derivative. Dirac believed that his solution to obtaining a first order theory, was simply too elegant to not be true and ended up prediction antimatter and the spin of fermions. |
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(Ken S. Tucker) wrote in message om...
(Gauge) wrote in message . com... I hope I'm not too tangential to the developement of this thread, but I'm still stuck on Pmb's 1st question.... Nah. I left this topic wide open with the broad label "Relativistic Quantum Mechanics" so feel free to indulge. I'm rather bored with the same-ole same-ole. Time for something new! :-) For example: Consider a frame, S, where there there is a uniform magnetic field. Has anyone every solved such a problem in closed form soution for a relativistic charged particle moving in such a field? Pmb You specified a "uniform magnetic field" and presuming the Electric field (F_0i) is zero Yes. The E-field is zero. ... then, Lorentz force is, f_i = qF_ij U^j , i,j = 1,2,3 U^j is 3-velocity, F_ij is the field tensor. Power = force x velocity = f_i U^i = 0 = qF_ij U^j U^i =0 (summing on an antisymmetrical tensor =0). Hold on there. Becareful with what you're calling "3-velocity." The quantinty "v" defined as v_x = dx/dt v_y = dy/dt v_z = dz/dt is what is normally called a 3-vector. The spatial part of the 4-velocity is not a 3-vector. They are related buy U^k = gamma*v_k Integrating ($) Power provides $ f_i dx^i = f_i x^i = $(qF_ij U^i U^j) ds = constant of integration = force x distance = energy. Radiation is usually described by Maxwell's F_uv;w + F_vw;u + F_wu;v = 0 It is? How so? ";" may be considered covariant or partial differentials in this case, and these require a changing field. In Pmb's example all field tensor components (F_uv) are constant, so there is no source of radiation, hence the charged particle is unable to alter it's energy or velocity. Hold on - There is the field the particle is moving in and there is the field of the particle. The field can basically be constant while it interacts with the particle. In the inertial frame S (the one in which there is only a uniform B field) the field does no work and therefore the energy of the particle is a constant. The velocity may change but the magnitude doesn't. Result - In S energy is conserved In another inertial frame, S' moving with with respect to S, there may be an electric field. If so then the field does work on the particle. Result - In S' energy is not conserved Conservation of energy is frame dependant for systems which are not closed. Energy can be conserved in one frame and not another. This is within a certain approximation of course since the particle looses radiation due to its acceleration. And of course this ignores the effect the particle has on the source etc. Here's where I maybe screwed up, I can't see how a charged particle can accelerate in a uniform magnetic field! It moves perpedicular to it. However - in electromagnetism - to generate power and energy, one must vary the relative field strengths as is done in a generator. That's not true in general. E.g. consider a uniform Electric fiedl. The force on a charge is F= qE. The power being delivered to the charge is P = Fv Now at this point, you might be thinking about Coulombs force law that acts similiar to gravitation. But I ask, how can a constant electric field produce radiation? It doesn't. Why should it? It's not field that's producing radiation. Its the particle which is accelerating. It gets its energy from whatever is generating the field. Pete |
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"Gauge" wrote in message om... (Ken S. Tucker) wrote in message om... (Gauge) wrote in message . com... I hope I'm not too tangential to the developement of this thread, but I'm still stuck on Pmb's 1st question.... Nah. I left this topic wide open with the broad label "Relativistic Quantum Mechanics" so feel free to indulge. I'm rather bored with the same-ole same-ole. Time for something new! :-) For example: Consider a frame, S, where there there is a uniform magnetic field. Has anyone every solved such a problem in closed form soution for a relativistic charged particle moving in such a field? Pmb You specified a "uniform magnetic field" and presuming the Electric field (F_0i) is zero Yes. The E-field is zero. ... then, Lorentz force is, f_i = qF_ij U^j , i,j = 1,2,3 U^j is 3-velocity, F_ij is the field tensor. Power = force x velocity = f_i U^i = 0 = qF_ij U^j U^i =0 (summing on an antisymmetrical tensor =0). Hold on there. Becareful with what you're calling "3-velocity." The quantinty "v" defined as v_x = dx/dt v_y = dy/dt v_z = dz/dt is what is normally called a 3-vector. The spatial part of the 4-velocity is not a 3-vector. They are related buy U^k = gamma*v_k Integrating ($) Power provides $ f_i dx^i = f_i x^i = $(qF_ij U^i U^j) ds = constant of integration = force x distance = energy. Radiation is usually described by Maxwell's F_uv;w + F_vw;u + F_wu;v = 0 It is? How so? ";" may be considered covariant or partial differentials in this case, and these require a changing field. In Pmb's example all field tensor components (F_uv) are constant, so there is no source of radiation, hence the charged particle is unable to alter it's energy or velocity. Hold on - There is the field the particle is moving in and there is the field of the particle. The field can basically be constant while it interacts with the particle. In the inertial frame S (the one in which there is only a uniform B field) the field does no work and therefore the energy of the particle is a constant. The velocity may change but the magnitude doesn't. Result - In S energy is conserved In another inertial frame, S' moving with with respect to S, there may be an electric field. If so then the field does work on the particle. Result - In S' energy is not conserved Conservation of energy is frame dependant for systems which are not closed. Energy can be conserved in one frame and not another. This is within a certain approximation of course since the particle looses radiation due to its acceleration. And of course this ignores the effect the particle has on the source etc. Hold on. Let me put that notion on hold Ken. While its' true that work is done in S' but not in S the systems may or may not be conservative Regarding frame dependance on conservation of energy - remember - this is *not* a closed system now. Consider the classical case from Newtonian mechancis - A completely elastic collision of a ball and a fixe wall. In the inertial frame moving with the ball after it bounces the ball is at rest in that frame. The energy of the ball, all of which is kinetic, is then zero. But the kinetic energy of the ball didn't become zero until the ball hit the wall. So it had energy before the bounce but not after. Energy is not conserved in that frame. In the frame rest frame of the wall the ball bounces and has the same kinetic energy before as after the collision What happened? Simple - In one frame the wall did no net work. In another frame the wall did net work.I.e. in one frame the dx in dW = F*dx is zero (wall frame) and in another frame dz is not zero and therefore does work in that frame. With systems that are not closed this things have to done carefully Pete |
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#10
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Gauge:
(Bilge) wrote in message e-al.net... Moreover, the hamiltonian is non-local, because it contains derivatives to all orders, so the space and time variables are not on equal footing. Yeah. That part I was aware of. So it's possible to use the Hamiltonian by taking the first few terms. However if there are an equal number of terms I don't see how that's a problem. I take it its a practical problem and not a theoretical. Please elaborate. To me this seems normal. Consider, in principle, the corresponding problem in non-relativistic quantum mechanics. In the postion representation there's no problem of course since there's only one second derivative There is not just a second order derivative. Each term containing p contains i\hbar\grad. So there are terms like \grad^2, \grad^4, etc. and with an abitrary potential its not a problem since the position operator has no derivatices in this representation. However consider the exact Hamiltonian but now in the momentum representation. As such the potential can, in principle, have a corresponding power series expansion which my have an infinite number of terms. In the momentum representation its now the postion operator which has derivatives and as such we're back to the same situation - A power series with an infinite number of terms. While not practical it's still meaningful and well defined. The meaning of the terms are not obvious. For example, you don't get any idea that there is something called "spin" just from the series expansion. As dirac factored it, the spin falls just out. In addition, when writing the dirac equation in its "natural" form, the operators (matrices) a and b are redefined by multiplying the entire equation through by b to get: (bE)\Psi = (ba + m)\Psi and one defines the \gamma (dirac) matrices by: b = \gamma^{0} ab = \gamma^{i}, i = 1,2,3 which then makes the connection of the spin as a relativistic feature completely transparent, since the \gamma matrices satisfy the following commutation and anti-commutation relations: [\gamma^{u}, \gamma^{v}]_{+} = 2g^{uv} [\gamma^{u}, \gamma^{v}] = 2i\sigma^{uv} where \sigma^{uv} is the spin tensor. From that, one can derive the allowable forms for a relativistic potential (interaction, that is), of which there are exactly five. For example, the electromagnetic current, j^{u} is ie\Psibar\gamma^{u}\Psi and the interaction with the four-vector potential is just j^{u}A_{u} = ie\Psibar\gamma^{u}\Psi A_{u} ==\Psibar A/\Psi (A/ == A-slash, the fourvector with a diagonal slash through it). One also gets the the four-vector identity for any two four-vectors, A_{u}, B_{u} contracted with \gamma matrices: A/ B/ = A^{u} B_{u} - 2i\sigma^{uv}A_{u}B_{v} from which the pauli identity can be obtained as a non-relativistic reduction. [...] You need to specify what you mean by "closed form solution". I've always seen and heard the term "closed form solution" to mean that the result is represented as a finite number of elementary functions. It does. What wasn';t clear was what solution you wanted in closed form. The dirac equation is the square root of p^2 + m^2 in closed form. That doesn't mean the solutions to the dirac equation will be in closed form. [...] The authors do say something to the effect that this problem is appropriately handled with the Dirac equation and indicate that what all falls out is that series. At least that's what I got from that section. Do you have this text? I owned both volumes at one time. I was going to throw both volumes into the trash, but someone offered to exchange both volumes for a copy of gottfried, so I took her up on the offer. I truly loathe that text, more than I can possibly describe. It spends 2000+ pages on the same material that is essentially covered in the first 200 pages of schiff and it does so with less clarity and less physical intuition. Both saxon and gasciorowicz (sp?) are much better textbooks, too. [...] If the particle is something like a pion do you still use the Dirac equation or is that strictly for particles with spin? Do you use the Klein-Gordon equation in that case? This is what my text seems to imply. The dirac equation only describes 1/2 integer spin particles. For spin 1/2, you you have the 4x4 dirac matrices. For spin 3/2 you have 8x8 matrices, and so on. The klein-gordon equation describes integer spin particles as well as 1/2 integer spin particles. Since the klein gordon hamiltonian is just the square of the dirac hamiltonian and it's also just the energy-momentum relations from relativity, the klein-gordon equation has to be satisfied by any particle in a relativistic theory. |
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