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| Tags: battery, lead |
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Lasse wrote: wrote in message Get an elementary electrical circuits book as it appears that's what you need to study before you can begin to ask reasonable questions. Well my concerns are a little bit more delicate than an elementary electrical circuits book can answer. According to elementary circuit theory you cannot have current without an applied voltage. But what about transport of charge through convection ...? Does convection apply to Ohms law ? As an electrical engineer I have problem answering that question. With the insufficent knowledge that I have in chemistry, I suspect(ed) that the lead battery can show current source behaviour. Go back to your book on tubes especially photo detectors similar equations will apply. A battery will have a space charge density around each electrode. The potential difference is of course the difference between the half-cell voltages. Now you need to throw in a transport equation through the acid for when there is a current and a chemical or ion density gradient. You can assume some time of mobility of the ions. This is where the non-linearity comes from as the mobility is not constant with current. I am sure if you ask someone at Everyready they will give you paper on it or look in the Electrochemical Journal. |
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