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Chemist Tries to Solve World's Energy Woes
By Brian Bergstein, AP Technology Writer Associated Press Yahoo! News Saturday, August 6, 2005 Cambridge, Mass. - A U.S. chemist is trying to determine how the world will produce enough energy to supply 9 billion people by mid-century -- and whether that can be done without pumping off-the-charts amounts of carbon dioxide into the air. Daniel Nocera, 48, is working to achieve an old, elusive dream: using the bountiful energy in sunlight to split water into its basic components, hydrogen and oxygen. The elements could then be used to supply clean-running fuel cells or new kinds of machinery. Or the energy created from the reaction itself, as atomic bonds are severed and re-formed, might be harnessed and stored. There is a beautiful model for this: photosynthesis. Sunlight kickstarts a reaction in which leaves break down water and carbon dioxide and turn them into oxygen and sugar, which plants use for fuel. But plants developed this process over billions of years, and even so, it's technically not that efficient. Nocera and other scientists are trying to replicate that -- and perhaps improve on it -- in decades. Hydrogen is the most abundant element in the universe, but it's generally locked up in compounds with other elements. Currently, it is chiefly harvested from fossil fuels, whose use is the main cause of carbon dioxide emissions blamed for global warming. And so while hydrogen fuel cells -- in which hydrogen and oxygen combine to produce electricity and water -- have a green reputation, their long-term promise could be limited unless the hydrogen they consume comes from clean sources. That's where Nocera's method comes in. If it works, it would be free of carbon and the epitome of renewable, since it would be powered by the sun. Enough energy from sunlight hits the earth every hour to supply the world for months. The challenge is harnessing it and storing it efficiently, which existing solar technologies do not do. "This is nirvana in energy. This will make the problem go away," Nocera said one morning in his office at the Massachusetts Institute of Technology, where the Grateful Dead devotee has a "Mean People Suck" sticker on his window. "If it doesn't, we will cease to exist as humanity." Lots of people have explored this challenge, but Nocera had a big breakthrough when he used light to coax multiple hydrogen atoms out of liquid. The key was figuring out the right chemical catalyst. Nocera's 2001 paper on the process in the journal Science, written with graduate student Alan Heyduk, turned heads. Venture capitalists rang his phone off the hook offering to fund him in an alternative-energy company. The achievement, and its revolutionary prospects, won Nocera this year's Italgas Prize, a $100,000 award given annually by an Italian utility to a top energy researcher. "Dan is even-money (odds) to solve this problem," says Harry Gray, a renowned California Institute of Technology chemist who was Nocera's graduate adviser. But there's a catch. In fact, there's a few, and they illustrate how hard it can be to move alternative energy beyond the proof-of-concept phase. Nocera has performed the reaction with acidic solutions, but not water yet. The catalyst he used was a compound that included the expensive metal rhodium. To be a practical energy solution, it will have to be made from inexpensive elements like iron, nickel or cobalt. Nocera's reaction got the photons in light to free up hydrogen atoms, but that's only half the equation. The harder part will be to also capture the oxygen that emerges when water molecules are split. That way, both elements can be fed into a fuel cell, making the process as efficient as possible. Nocera and scientists not affiliated with his work say those steps are achievable. But first, major advances in basic chemistry will be necessary for the reactions to be well understood. As a result, Nocera believes it might be 20 years before engineers might design systems based on his work. And he frets that too few scientists are exploring the problem, with many top minds instead focused on biomedical research. "This is a massive construction project," he says. "You can go back to building New York City in the '20s and '30s. You can't do it with just a few construction workers. So I need more construction workers, more hard hats, with me as a hard hat." There's another big hurdle. While Nocera plugs away at trying to save the world, some people don't believe it needs saving. Most scientists concur that continuing to burn fossil fuels will send the amount of carbon dioxide in the atmosphere -- it's now 35 percent higher than in preindustrial times -- to dangerous levels, causing global temperatures to rise with potentially devastating effects. "We are literally poisoning ourselves," Nocera says. "People don't get it because they can't see it." But this is a famously politicized topic in the United States, where some powerful political leaders question the science behind global warming. And that, many scientists say, diverts attention and funds from trying to solve the problem. And even among people who believe global warming's risks are too great to ignore, there is no consensus on what kind of green energy should come to the rescue. Nocera cites a calculation by Caltech chemist Nathan Lewis that power demands in 2050 will be so great that just to keep carbon dioxide emissions at twice preindustrial levels, a nuclear plant would have to be built every two days. There's not enough room on the planet's surface for other widely touted solutions such as wind and biomass to have much impact. Only the sun is the answer, Lewis argues. Critics of that vision say many energy technologies being explored -- including improved ways of storing electricity and different kinds of fuel cells -- will come online in the next few decades and throw off today's extrapolations about the future. Arno Penzias, who won the Nobel Prize for confirming the Big Bang and now invests in alternative energy startups for New Enterprise Associates, contends there are dozens of ideas more promising than ones involving hydrogen. When told about Nocera's project, Penzias gets heated, saying it is unlikely to be practical. "It is so far from being revolutionary that it's not even worth mentioning," Penzias says. "It will be a big yawn." Nocera seems to thrive on such opposition, because he expects to prove naysayers wrong. It's part of his blunt enthusiasm, which manifests itself when he discusses the joys of teaching chemistry to freshmen ("They love me") or when he meets with his grad students to discuss the status of their research. Those sessions often devolve into arguments over the meaning of some data or the direction that projects ought to take. Provoked by Nocera's intensity -- he'll exclaim, "I'm dying here!" in a tone resembling neurotic comic Larry David -- tempers often rise. One student recently threw an eraser at Nocera, leaving a pink welt on his back that Nocera later showed off with a laugh. "There were times I absolutely hated working for him, because he knew how to press all of my buttons and drive me absolutely insane," says Heyduk, now assistant professor of chemistry at the University of California, Irvine. "He knew I was the kind of person that needed to be challenged all the time." Nocera believes this constant prodding at what's possible is the essence of science. As evidence, he reels off several ancillary developments from his research, including microscopic sensors that detect biological hazards, which attracted funding from the Defense Advanced Research Projects Agency. Pointing to a whiteboard sketch of his vision for using sunlight to split water, Nocera acknowledges that it ultimately might not be an energy panacea. "Is it right? Maybe not. But it will be something. And it might be something I can't see right now," he says. "That's OK. But you don't stop doing something because you can't see it. It's antiscientific. It's anti- intellectual." More at: http://news.yahoo.com/s/ap/20050806/...energy_chemist Jai Maharaj http://www.mantra.com/jai Om Shanti Hindu Holocaust Museum http://www.mantra.com/holocaust Hindu life, principles, spirituality and philosophy http://www.hindu.org http://www.hindunet.org The truth about Islam and Muslims http://www.flex.com/~jai/satyamevajayate The terrorist mission of Jesus stated in the Christian bible: "Think not that I am come to send peace on earth: I came not so send peace, but a sword. "For I am come to set a man at variance against his father, and the daughter against her mother, and the daughter in law against her mother in law. "And a man's foes shall be they of his own household. - Matthew 10:34-36. o Not for commercial use. Solely to be fairly used for the educational purposes of research and open discussion. The contents of this post may not have been authored by, and do not necessarily represent the opinion of the poster. The contents are protected by copyright law and the exemption for fair use of copyrighted works. o If you send private e-mail to me, it will likely not be read, considered or answered if it does not contain your full legal name, current e-mail and postal addresses, and live-voice telephone number. o Posted for information and discussion. Views expressed by others are not necessarily those of the poster who may or may not have read the article. FAIR USE NOTICE: This article may contain copyrighted material the use of which may or may not have been specifically authorized by the copyright owner. This material is being made available in efforts to advance the understanding of environmental, political, human rights, economic, democratic, scientific, social, and cultural, etc., issues. It is believed that this constitutes a 'fair use' of any such copyrighted material as provided for in section 107 of the US Copyright Law. In accordance with Title 17 U.S.C. Section 107, the material on this site is distributed without profit to those who have expressed a prior interest in receiving the included information for research, comment, discussion and educational purposes by subscribing to USENET newsgroups or visiting web sites. For more information go to: http://www.law.cornell.edu/uscode/17/107.shtml If you wish to use copyrighted material from this article for purposes of your own that go beyond 'fair use', you must obtain permission from the copyright owner. Since newsgroup posts are being removed by forgery by one or more net terrorists, this post may be reposted several times. |
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#2
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Chemist Tries to Solve World's Energy Woes
By Brian Bergstein, AP Technology Writer Associated Press Yahoo! News Saturday, August 6, 2005 Cambridge, Mass. - A U.S. chemist is trying to determine how the world will produce enough energy to supply 9 billion people by mid-century -- and whether that can be done without pumping off-the-charts amounts of carbon dioxide into the air. Daniel Nocera, 48, is working to achieve an old, elusive dream: using the bountiful energy in sunlight to split water into its basic components, hydrogen and oxygen. The elements could then be used to supply clean-running fuel cells or new kinds of machinery. Or the energy created from the reaction itself, as atomic bonds are severed and re-formed, might be harnessed and stored. There is a beautiful model for this: photosynthesis. Sunlight kickstarts a reaction in which leaves break down water and carbon dioxide and turn them into oxygen and sugar, which plants use for fuel. But plants developed this process over billions of years, and even so, it's technically not that efficient. Nocera and other scientists are trying to replicate that -- and perhaps improve on it -- in decades. Hydrogen is the most abundant element in the universe, but it's generally locked up in compounds with other elements. Currently, it is chiefly harvested from fossil fuels, whose use is the main cause of carbon dioxide emissions blamed for global warming. And so while hydrogen fuel cells -- in which hydrogen and oxygen combine to produce electricity and water -- have a green reputation, their long-term promise could be limited unless the hydrogen they consume comes from clean sources. That's where Nocera's method comes in. If it works, it would be free of carbon and the epitome of renewable, since it would be powered by the sun. Enough energy from sunlight hits the earth every hour to supply the world for months. The challenge is harnessing it and storing it efficiently, which existing solar technologies do not do. "This is nirvana in energy. This will make the problem go away," Nocera said one morning in his office at the Massachusetts Institute of Technology, where the Grateful Dead devotee has a "Mean People Suck" sticker on his window. "If it doesn't, we will cease to exist as humanity." Lots of people have explored this challenge, but Nocera had a big breakthrough when he used light to coax multiple hydrogen atoms out of liquid. The key was figuring out the right chemical catalyst. Nocera's 2001 paper on the process in the journal Science, written with graduate student Alan Heyduk, turned heads. Venture capitalists rang his phone off the hook offering to fund him in an alternative-energy company. The achievement, and its revolutionary prospects, won Nocera this year's Italgas Prize, a $100,000 award given annually by an Italian utility to a top energy researcher. "Dan is even-money (odds) to solve this problem," says Harry Gray, a renowned California Institute of Technology chemist who was Nocera's graduate adviser. But there's a catch. In fact, there's a few, and they illustrate how hard it can be to move alternative energy beyond the proof-of-concept phase. Nocera has performed the reaction with acidic solutions, but not water yet. The catalyst he used was a compound that included the expensive metal rhodium. To be a practical energy solution, it will have to be made from inexpensive elements like iron, nickel or cobalt. Nocera's reaction got the photons in light to free up hydrogen atoms, but that's only half the equation. The harder part will be to also capture the oxygen that emerges when water molecules are split. That way, both elements can be fed into a fuel cell, making the process as efficient as possible. Nocera and scientists not affiliated with his work say those steps are achievable. But first, major advances in basic chemistry will be necessary for the reactions to be well understood. As a result, Nocera believes it might be 20 years before engineers might design systems based on his work. And he frets that too few scientists are exploring the problem, with many top minds instead focused on biomedical research. "This is a massive construction project," he says. "You can go back to building New York City in the '20s and '30s. You can't do it with just a few construction workers. So I need more construction workers, more hard hats, with me as a hard hat." There's another big hurdle. While Nocera plugs away at trying to save the world, some people don't believe it needs saving. Most scientists concur that continuing to burn fossil fuels will send the amount of carbon dioxide in the atmosphere -- it's now 35 percent higher than in preindustrial times -- to dangerous levels, causing global temperatures to rise with potentially devastating effects. "We are literally poisoning ourselves," Nocera says. "People don't get it because they can't see it." But this is a famously politicized topic in the United States, where some powerful political leaders question the science behind global warming. And that, many scientists say, diverts attention and funds from trying to solve the problem. And even among people who believe global warming's risks are too great to ignore, there is no consensus on what kind of green energy should come to the rescue. Nocera cites a calculation by Caltech chemist Nathan Lewis that power demands in 2050 will be so great that just to keep carbon dioxide emissions at twice preindustrial levels, a nuclear plant would have to be built every two days. There's not enough room on the planet's surface for other widely touted solutions such as wind and biomass to have much impact. Only the sun is the answer, Lewis argues. Critics of that vision say many energy technologies being explored -- including improved ways of storing electricity and different kinds of fuel cells -- will come online in the next few decades and throw off today's extrapolations about the future. Arno Penzias, who won the Nobel Prize for confirming the Big Bang and now invests in alternative energy startups for New Enterprise Associates, contends there are dozens of ideas more promising than ones involving hydrogen. When told about Nocera's project, Penzias gets heated, saying it is unlikely to be practical. "It is so far from being revolutionary that it's not even worth mentioning," Penzias says. "It will be a big yawn." Nocera seems to thrive on such opposition, because he expects to prove naysayers wrong. It's part of his blunt enthusiasm, which manifests itself when he discusses the joys of teaching chemistry to freshmen ("They love me") or when he meets with his grad students to discuss the status of their research. Those sessions often devolve into arguments over the meaning of some data or the direction that projects ought to take. Provoked by Nocera's intensity -- he'll exclaim, "I'm dying here!" in a tone resembling neurotic comic Larry David -- tempers often rise. One student recently threw an eraser at Nocera, leaving a pink welt on his back that Nocera later showed off with a laugh. "There were times I absolutely hated working for him, because he knew how to press all of my buttons and drive me absolutely insane," says Heyduk, now assistant professor of chemistry at the University of California, Irvine. "He knew I was the kind of person that needed to be challenged all the time." Nocera believes this constant prodding at what's possible is the essence of science. As evidence, he reels off several ancillary developments from his research, including microscopic sensors that detect biological hazards, which attracted funding from the Defense Advanced Research Projects Agency. Pointing to a whiteboard sketch of his vision for using sunlight to split water, Nocera acknowledges that it ultimately might not be an energy panacea. "Is it right? Maybe not. But it will be something. And it might be something I can't see right now," he says. "That's OK. But you don't stop doing something because you can't see it. It's antiscientific. It's anti- intellectual." More at: http://news.yahoo.com/s/ap/20050806/...energy_chemist Jai Maharaj http://www.mantra.com/jai Om Shanti Hindu Holocaust Museum http://www.mantra.com/holocaust Hindu life, principles, spirituality and philosophy http://www.hindu.org http://www.hindunet.org The truth about Islam and Muslims http://www.flex.com/~jai/satyamevajayate The terrorist mission of Jesus stated in the Christian bible: "Think not that I am come to send peace on earth: I came not so send peace, but a sword. "For I am come to set a man at variance against his father, and the daughter against her mother, and the daughter in law against her mother in law. "And a man's foes shall be they of his own household. - Matthew 10:34-36. o Not for commercial use. Solely to be fairly used for the educational purposes of research and open discussion. The contents of this post may not have been authored by, and do not necessarily represent the opinion of the poster. The contents are protected by copyright law and the exemption for fair use of copyrighted works. o If you send private e-mail to me, it will likely not be read, considered or answered if it does not contain your full legal name, current e-mail and postal addresses, and live-voice telephone number. o Posted for information and discussion. Views expressed by others are not necessarily those of the poster who may or may not have read the article. FAIR USE NOTICE: This article may contain copyrighted material the use of which may or may not have been specifically authorized by the copyright owner. This material is being made available in efforts to advance the understanding of environmental, political, human rights, economic, democratic, scientific, social, and cultural, etc., issues. It is believed that this constitutes a 'fair use' of any such copyrighted material as provided for in section 107 of the US Copyright Law. In accordance with Title 17 U.S.C. Section 107, the material on this site is distributed without profit to those who have expressed a prior interest in receiving the included information for research, comment, discussion and educational purposes by subscribing to USENET newsgroups or visiting web sites. For more information go to: http://www.law.cornell.edu/uscode/17/107.shtml If you wish to use copyrighted material from this article for purposes of your own that go beyond 'fair use', you must obtain permission from the copyright owner. Since newsgroup posts are being removed by forgery by one or more net terrorists, this post may be reposted several times. |
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#3
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"Dr. Jai Maharaj" wrote in message news:QeArO4647ItIno@TsiUf... Chemist Tries to Solve World's Energy Woes By Brian Bergstein, AP Technology Writer Associated Press Yahoo! News Saturday, August 6, 2005 Cambridge, Mass. - A U.S. chemist is trying to determine how the world will produce enough energy to supply 9 billion people by mid-century -- and whether that can be done without pumping off-the-charts amounts of carbon dioxide into the air. Snip....... A direct quite from the article: "Hydrogen is the most abundant element in the universe, but it's generally locked up in compounds with other elements. Currently, it is chiefly harvested from fossil fuels, whose use is the main cause of carbon dioxide emissions blamed for global warming." This idiotic and absolutely meaningless statement is a red flag that the article may be devoid of facts or that it is a serious statement of actual science being pursued. When one resorts to this statement it illustrates that the writer has little clue about the science being reported and, in general, is blowing smoke at an unsophisticated audience. Hydrogen is far from the most abundant element on earth where we happen to live. If abundance were an issue, silicon, aluminum or iron would be among the elements of choice, not hydrogen. Clearly making that statement calls into question other facts and assumptions of the article and is a warning that the article may not contain much useful information. Bob |
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#4
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"Daniel Nocera, 48, is working to achieve an old, elusive
dream: using the bountiful energy in sunlight to split water into its basic components, hydrogen and oxygen. The elements could then be used to supply clean-running fuel cells or new kinds of machinery. Or the energy created from the reaction itself, as atomic bonds are severed and re-formed, might be harnessed and stored. There is a beautiful model for this: photosynthesis. Sunlight kickstarts a reaction in which leaves break down water and carbon dioxide and turn them into oxygen and sugar, which plants use for fuel. But plants developed this process over billions of years, and even so, it's technically not that efficient. Nocera and other scientists are trying to replicate that -- and perhaps improve on it -- in decades" Solar cells are about 100 times more efficeint than photosynthesis. Why not just hook up a few solar panels to an electrolyzer? It looks like Dr. Nocera is trying to build a more efficient solar cell? The world has more important problems than running out of energy. The world is running out of food. One solution: http://www.verticalfarm.com |
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#5
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Bob Eldred wrote:
Chemist Tries to Solve World's Energy Woes By Brian Bergstein, AP Technology Writer Associated Press Yahoo! News Saturday, August 6, 2005 Cambridge, Mass. - A U.S. chemist is trying to determine how the world will produce enough energy to supply 9 billion people by mid-century -- and whether that can be done without pumping off-the-charts amounts of carbon dioxide into the air. Snip....... A direct quite from the article: "Hydrogen is the most abundant element in the universe, but it's generally locked up in compounds with other elements. Currently, it is chiefly harvested from fossil fuels, whose use is the main cause of carbon dioxide emissions blamed for global warming." This idiotic and absolutely meaningless statement is a red flag that the article may be devoid of facts or that it is a serious statement of actual science being pursued. When one resorts to this statement it illustrates that the writer has little clue about the science being reported and, in general, is blowing smoke at an unsophisticated audience. Hydrogen is far from the most abundant element on earth where we happen to live. I think the article doesn't make that claim. It says, correctly, that "Hydrogen is the most abundant element in the universe". I think you should look at this: http://www.webelements.com/webelemen...xt/H/geol.html http://www.ucsusa.org/clean_energy/h....cfm?pageID=88 |
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#7
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"Dr. Homilete" wrote in message news:CNNJe.4104$lK2.2258@trndny01...
Bob Eldred wrote: Chemist Tries to Solve World's Energy Woes Cambridge, Mass. - A U.S. chemist is trying to determine how the world will produce enough energy to supply 9 billion people by mid-century -- and whether that can be done without pumping off-the-charts amounts of carbon dioxide into the air. A direct quite from the article: "Hydrogen is the most abundant element in the universe, but it's generally locked up in compounds with other elements. Currently, it is chiefly harvested from fossil fuels, whose use is the main cause of carbon dioxide emissions blamed for global warming." Most hydrogen is useless because it is locked in H2O. However, trillions of tons of biomass have usable C+H. This idiotic and absolutely meaningless statement is a red flag that the article may be devoid of facts or that it is a serious statement of actual science being pursued. When one resorts to this statement it illustrates that the writer has little clue about the science being reported and, in general, is blowing smoke at an unsophisticated audience. Hydrogen is far from the most abundant element on earth where we happen to live. There is more than enough hydrogen, but it isn't H2, convient, or cheap. Yes, anyone who claims "hydrogen is abundant" is an idiot. I think the article doesn't make that claim. It says, correctly, that "Hydrogen is the most abundant element in the universe". I think you should look at this: http://www.webelements.com/webelemen...xt/H/geol.html http://www.ucsusa.org/clean_energy/h....cfm?pageID=88 We don't live in space, do we? We have to make due with earth's resources. |
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#8
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Uncle Al wrote: Because you cannot do aritmetic, git. The average solar cell over its average operating life does not return the energy used in its fabrication and deployment. Solar cells are all about in situ convenience. Then the average solar cell is not fully utilized. Here is an energy payback study of solar cells that are fully utilized: http://www.nrel.gov/ncpv/pdfs/24596.pdf It is not the energy payback of solar that's the problem. It is the return on investment. At around $25 a net watt, they are almost ten times more expensive than coal. Area necessary to generate 1 GW electrical, theoretical minimum Area, mi^2 Modality ==================== 1000 biomass ? didn't check. But I've crunched crop fuel numbers and they don't add up. 300 wind Assumes the land between turbines isn't utilized? Sounds like a number from the energy advocate. They can be scattered in farm lands. 60 solar crunch. http://rredc.nrel.gov/solar/old_data...redbook/atlas/ Fixed flat panel in AZ, call it 6kwh/day/m^2. 16% cells, 1kwh/day/m^2. So 24E6m^2. Or 9mi^2 for 1 GW. Last time I crunch numbers I found there was 2 to 3 times as much land dedicated to easements as would be required to supply all our energy needs, including EV transportation. Put a square 60 miles on a side in arizona to get a feel. Nope, it isn't energy payback or land. It is cost. 0.3 nuclear Ok. P.S. The only practical thing I can see from here is that wind could contribute 10% of grid demand in twenty years. Our real salvation is nuclear. Then we make coal last longer for transportation fuels. It is likely to take more than a century before we learn to get along without fossil fuels. (If we ever do...) Best, Dan. -- Add one for email |
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#9
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#10
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"Dr. Homilete" wrote in message news:CNNJe.4104$lK2.2258@trndny01... I think the article doesn't make that claim. It says, correctly, that "Hydrogen is the most abundant element in the universe". I think you should look at this: I got news for you. It doesn't matter what the abundance of elements in the universe are....It only matters what we have access to. Maybe you can get your hydrogen from Jupiter or the Sun or the Orion nebula but most of us are earth bound and hydrogen is way down the list on earth so the statement while true is stupid and meaningless. Furthermore making that statement shows an utter disregard for where the element comes from or the energy required to extract it. It gives the impression that hydrogen is just there for the plucking. Meaning less as it is, that statement seems to crop up in all kinds of popular literature on the subject. In fact, my point was that seeing that statement is a dead giveaway that one is dealing with a popular science type article and not a professional level discussion of the subject. When you see it, there is little point in reading any further. |
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