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| Tags: dielectric |
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#1
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If two electrodes are sandwitching two dielectric materials with very
different dielectric constants (but the same thickness), say, water and glass. Would the new dielectric constant lies in between the original two? What would be the electric field in between the dielectric materials? I suppose not half of the total electric field imposed by the electrodes. Would the larger dielectric constant material take up more of it? If the water contains ions, would that change its dielectric constant from that of its pure form (about 80)? Is there any relation between dielectric constant and dielectric strength? |
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#2
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Dear rambotrout:
On Jun 12, 11:53*am, rambotrout wrote: If two electrodes are sandwitching two dielectric materials with very different dielectric constants (but the same thickness), say, water and glass. ... better, air and glass. Would the new dielectric constant lies in between the original two? Yes. Over the total separation. What would be the electric field in between the dielectric materials? No change, I think. The electric field is impressed by the charge on the plates. The amount of energy involved in impressing that particular field, that is something else again. I suppose not half of the total electric field imposed by the electrodes. Would the larger dielectric constant material take up more of it? The dielectric controls the current that will flow for a given applied voltage. If the water contains ions, would that change its dielectric constant from that of its pure form (about 80)? No, it controls its "leakage" or resistivity. Is there any relation between dielectric constant and dielectric strength? Not really, or at least not directly. http://www.ami.ac.uk/courses/topics/0184_dp/index.html http://en.wikipedia.org/wiki/Dielectric_strength http://en.wikipedia.org/wiki/Dielectric_constant Dielectric strength has to do with the strength of the weakest bond. Dielectric constant has to do with how polar an atom or molecule is. David A. Smith |
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#3
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What would be the electric field in between the
dielectric materials? No change, I think. The electric field is impressed by the charge on the plates. The amount of energy involved in impressing that particular field, that is something else again. Do you mean it follows the Coulumb's law without being affected by the dielectric material? I thought (but I may be wrong) the dielectric material would change the electric field in the material as the law is derived for the vacumm case. The Coulumb constant is affected by electric constant (vacumm permittivity) and a dielectric constant is the ratio of static permittivity of the material and electric constant. I am pretty sure it does change something just like it affects the capacitance. If the water contains ions, would that change its dielectric constant from that of its pure form (about 80)? No, it controls its "leakage" or resistivity. I don't think I am getting an answer. Assume that the electrodes are thinly insulated so as to block current leakage. Would water with ions in it still retain its dielectric constant of 80? |
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#4
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Dear rambotrout:
On Jun 12, 2:40*pm, rambotrout wrote: What would be the electric field in between the dielectric materials? No change, I think. *The electric field is impressed by the charge on the plates. *The amount of energy involved in impressing that particular field, that is something else again. Do you mean it follows the Coulumb's law without being affected by the dielectric material? I thought (but I may be wrong) the dielectric material would change the electric field in the material as the law is derived for the vacumm case. The Coulumb constant is affected by electric constant (vacumm permittivity) and a dielectric onstant is the ratio of static permittivity of the material and electric constant. I am pretty sure it does change something just like it affects the capacitance. The electric field is governed by the charge on the plates. I had assumed you left a "battery " connected, and were interested only in how the "electric field" was distributed within the medium. Maybe you need to wait on a better answer on this one from someone lese. If the water contains ions, would that change its dielectric constant from that of its pure form (about 80)? No, it controls its "leakage" or resistivity. I don't think I am getting an answer. Assume that the electrodes are thinly insulated so as to block current leakage. Would water with ions in it still retain its dielectric constant of 80? http://lists.contesting.com/_topband.../msg00111.html fresh water, k = 80. salt water, k = 81. The k value describes how the material stores energy under an electric field. The water molecule "deforms", as well as aligning. Ions will only align. David A. Smith |
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#5
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On Jun 13, 2:37 am, John C. Polasek wrote:
On Thu, 12 Jun 2008 11:53:10 -0700 (PDT), rambotrout wrote: If two electrodes are sandwitching two dielectric materials with very different dielectric constants (but the same thickness), say, water and glass. Would the new dielectric constant lies in between the original two? You can insert a 3d plate in the sandwich, then analyze 2 capacitors in series. The charge Q and displacement D = Q/A = Ei*Ki/A are constant throughout including on the plates. The individual voltages are inverse to the dielectric constant. Vi = Ei*Ti (T = thickness. A = area). What are Ki and Ei? How do you get displace D = Q/A? |
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#6
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On Thu, 12 Jun 2008, rambotrout wrote:
What would be the electric field in between the dielectric materials? No change, I think. The electric field is impressed by the charge on the plates. The amount of energy involved in impressing that particular field, that is something else again. Do you mean it follows the Coulumb's law without being affected by the dielectric material? I thought (but I may be wrong) the dielectric material would change the electric field in the material as the law is derived for the vacumm case. The Coulumb constant is affected by electric constant (vacumm permittivity) and a dielectric constant is the ratio of static permittivity of the material and electric constant. I am pretty sure it does change something just like it affects the capacitance. For Coulomb's law in a dielectric medium, the D-field (i.e., the electric displacement) is unaffected by the medium (recall that the relevant Maxwell equation is div(D) = rho, where rho is the free charge density). Since D = eE, e = permittivity, E is reduced as e increases. The electric force is F = qE, so the force is reduced. Just use e instead of e0 in Coulomb's law (Coulomb's constant being 1/(4*pi*e0)). As your your original question, what stays constant? The charge on the plates? Or the voltage across them? If Q is constant, then D will remain the same, and it'll be easy to find E everywhere between the plates. When you know E, you can find the potential V at any point easily. Since we know that the field between two parallel plates in free space (ignoring edge effects) is E = (Q/A)/e0, we have D=Q/A. For V held constant, then you have V = E1*d1 + E2*d2, where E1 and E2 are the fields within the dielectrics, and d1 and d2 are the thicknesses. E1 and E2 are both unknown, but the continuity of D (basically, D1=D2, which gives e1*E1 = e2*E2) gives the required extra equation. This will work for as many layers as you care to include. If you want an "average"/"effective" dielectric constant, how do you want to define it? The "average" E can be taken to be E_eff = V/distance = V/(d1+d2), D is constant, so D = e_eff E_eff looks good. If the water contains ions, would that change its dielectric constant from that of its pure form (about 80)? No, it controls its "leakage" or resistivity. I don't think I am getting an answer. Assume that the electrodes are thinly insulated so as to block current leakage. Would water with ions in it still retain its dielectric constant of 80? Water with ions is conductive. If there are enough ions, you can treat it as a perfect conductor - the conductivity will be high enough so the charge distribution in the water will reach equilibrium. What is the dielectric constant of a perfect conductor? If the number of ions is small enough, the conductivity will be low enough so that it can be ignored for reasonable times. If the ions don't move significantly, don't expect any major effect on the dielectric constant. Somewhere in between would be the difficult case where you can't treat the water+field as an electrostatic problem (unlike both the perfect conductor and insulator limits) since equilibrium would not be reached during the times of interest. -- Timo Nieminen - Home page: http://www.physics.uq.edu.au/people/nieminen/ E-prints: http://eprint.uq.edu.au/view/person/...,_Timo_A..html Shrine to Spirits: http://www.users.bigpond.com/timo_nieminen/spirits.html |
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#7
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Thank you everyone for all the replies.
I have better grasp of it now. Timo, if the electrode is thinly insulated, wouldn't all the ions get attracted very close to their respective electrodes thus leaving the water "relatively" pure? In this case, wouldn't the dielectric constant of the water is retained? |
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#8
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Dear rambotrout:
"rambotrout" wrote in message ... Thank you everyone for all the replies. I have better grasp of it now. Timo, if the electrode is thinly insulated, wouldn't all the ions get attracted very close to their respective electrodes thus leaving the water "relatively" pure? Yes. "Electrodeionization". In this case, wouldn't the dielectric constant of the water is retained? Yes, as I gave you numbers befo pure water, k = 80 salt water, k = 81 David A. Smith |
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#9
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Dear John C. Polasek:
On Jun 19, 6:48*am, John C. Polasek wrote: ... Timo, if the electrode is thinly insulated, wouldn't all the ions get attracted very close to their respective electrodes thus leaving the water "relatively" pure? Yes. *"Electrodeionization". In this case, wouldn't the dielectric constant of the water is retained? Yes, as I gave you numbers befo pure water, k = 80 salt water, k = 81 The water might break down under fairly weak fields because K = 80 is a very high number for a simple natural substance. They are two different measures. Water is polar, so without breaking down it can rotate to where most of the oxygen atoms are preferentially oriented towards the anode. What this means is that the bound electrons are on very weak "springs" and have large deflections (K = 80) so that a moderate field might break the springs and free the electron for conduction. No. You are conflating conduction or conductivity with permittivity. In conduction (your "breakdown"), electrons / ions are free to migrate through the material the electric field is applied to. In permittivity, the material undergos a "physical" change NOT requiring the motion of loose charges. Roughly, imagine a bunch of frozen chickens hanging from "pegs" inside an enclosure in empty space. The chickens will be randomly oriented. Now move it into a gravity field, and the chickens will hang "down". In this (silly) analog, the center of mass is slightly lower in the graivtational field... because the average chicken is closer to the "bottom". This is how energy is liberated from "charging" a dielectric. If the battery remains connected, the E field is still there, exacerbated by local ionizations, and able to do more ionization rather than herding ions where they can't do any harm. Mobile ions / electrons serve to reduce the field in the dielectric, since they tend to hover very near the plate. What is "thinly insulated"? For a capacitive cell, with a dielectric thickness t_d, and "thin insulator" thickness t_i: 2 * t_i t_d David A. Smith |
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#10
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Dear John C. Polasek:
On Jun 19, 1:34*pm, John C. Polasek wrote: On Thu, 19 Jun 2008 07:30:59 -0700 wrote: On Jun 19, 6:48*am, John C. Polasek wrote: ... What this means is that the bound electrons are on very weak "springs" and have large deflections (K = 80) so that a moderate field might break the springs and free the electron for conduction. No. *You are conflating conduction or conductivity with permittivity. In conduction (your "breakdown"), electrons / ions are free to migrate through the material the electric field is applied to. *In permittivity, the material undergos a "physical" change NOT requiring the motion of loose charges. You seem unable to read a sentence: I am saying you have permittivity as long as the electrons remain elastically bound, (and thus able to store energy) but upon their breaking loose you have the ohmic condition. I can read a sentence. You veered off from permittivity to discussing breakdown. This is not what the OP asked about. Additionally, the Rube Goldberg device you construct, relating high k value (loose springs) to low dielectric breakdown voltage does not pan out. ... This sentence doesn't parse: This is how energy is liberated from "charging" a dielectric. Please explain, preferably without the assistsance of poultry. In general, the water molecules (in this case) do not get closer together, they simply orient themsleves with the oxygen atoms facing the anode. The analogy you ceased to be humored by used gravitation in place of an applied E field. In a material, alignment of charges yields energy... like the "latent heat of fusion" of a salt, for example. ... If the battery remains connected, the E field is still there, exacerbated by local ionizations, and able to do more ionization rather than herding ions where they can't do any harm. Mobile ions / electrons serve to reduce the field in the dielectric, since they tend to hover very near the plate. Any incidence of shortening the gap, as I assume could occur with ions Not really, no. They really will "plate out" on the electrode about as close as possible. will necessarily raise the field intensity elsewhere Absolutely not. The ions themselves have opposite sign, and *directly reduce* the E-field. The are not polar, that have a single (sometimes more) unbalanced charge. with possible avalanche results. What is "thinly insulated"? For a capacitive cell, with a dielectric thickness t_d, and "thin insulator" thickness t_i: 2 * t_i t_d So at least in your opinion I answered that one... David A. Smith |
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